Free radical polymerization can be iniitated by thermal chemical or photolytic decomposition of initiator molecules. The propagation kinetics of radical homopolymerization bulk of vinyl acetate vac vinyl pivalate vpi and vinyl benzoate vbz was studied using pulsed laser polymerization coupled with size exclusion chromatography plp sec at laser pulse repetition. In order to demonstrate the retention of xanthate chain end functionality during the madix polymerizations in ethyl acetate pvac macromonomers prepared with m 0 cta 0 100 in ethyl acetate were chain extended with vinyl acetate monomer under reaction conditions m 0 macro cta 0 aibn 0 300 1 0 2 or 1200 1 0 2.
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